Artificial intelligence (AI) has become increasingly popular as a tool to model, identify, optimize, forecast, and control renewable energy systems. This work aimed to evaluate the capability of the artificial neural network (ANN) procedure to model and forecast solar power outputs of photovoltaic power systems (PVPSs) by using meteorological data. For this purpose, based on the literature review, important factors affecting energy generation in a PVPS were selected as inputs, and a recurrent neural network (RNN) architecture was established. After completing the trained network, the RNN capability was assessed to predict the energy output of the PVPS for days not included in the training database. The performance evaluation of the trained RNN revealed a regression value of 0.97774 for test data, whereas the RMSE and the mean actual output power for a sample day were 0.0248 MJ and 0.538 MJ, respectively. In addition to RMSE, an error histogram and regression plots obtained by MATLAB were employed to evaluate the network’s capability, and validation results represented a sufficient prediction accuracy of the trained RNN.