This paper presents the possibility of the energetic utilization of biowaste in the form of lignified one-year shoots from the cultivation of grapevines of the Seyval Blanc (WSBL), Solaris (WSOL), Regent (WREG) and Rondo (WRON) varieties, grown in temperate climate zones. A technical analysis, an elemental analysis and the determination of the highest heat value and lowest heat value were performed to define the quality parameters of waste as fuel. In addition, the emission factors of SO2, NOx, CO, CO2 and dust were estimated to demonstrate the impact of potential biowaste from combustion. Based on the stoichiometric equations, the exhaust gas composition, the theoretical oxygen demand and the total flue gas volume were evaluated. The study showed that the material with the highest energy potential was WREG (LHV-16.19 MJ·kg−1), with an ash content of 3.68%, while the lowest potential was found for WRON (LHV-15.88 MJ·kg−1), with an ash content of 4.21%. The study showed that the use of the studied viticulture waste instead of hard coal could reduce CO emissions by 26–27%, CO2 by 24–26%, NOx by 55–56%, SO2 by 96–97% and dust by 77–80%.