Kinetics of manganese sorption on ukrainian tuff and basalt - order and diffusion models analysis

Abstrakt

The study aimed to determine the nature of the kinetics of the manganese sorption process on Ukrainian tuff and basalt at different temperatures characteristic of the natural water environment. The scope of the research included manganese sorption kinetic test on natural mineral sorbents at temperatures of 10, 17.5 and 25 °C in slightly acidic conditions. Sorption (pseudo-first order, pseudo-second order and Elovich models) and diffusion kinetic models (liquid film diffusion and intraparticle diffusion) were used in the analysis of test results. The manganese sorption process on both tuff and basalt proceeded quickly. The dynamic equilibrium state of manganese sorption settled after 35 and 45 min on tuff and basalt respectively. Although the process took place in a slightly acidic environment and below pHPZC of the sorbents, possible electrostatic repulsion did not inhibit the removal of Mn. The Mn sorption on both materials followed the PSO kinetics model. Based on the diffusion kinetic models, it was determined that Mn sorption process on both materials was influenced by diffusion through the boundary layer and intraparticle diffusion. The differences in removal efficiency and rate of Mn sorption in the temperature range of 10–25 °C were not found.

Autorzy

Lidia Reczek
Lidia Reczek
Magdalena M. Michel
Magdalena M. Michel
Yuliia Trach
Yuliia Trach
Marta Tytkowska-Owerko
Marta Tytkowska-Owerko
artykuł
Minerals
Angielski
2020
10
12
1065
otwarte czasopismo
CC BY 4.0 Uznanie autorstwa 4.0
ostateczna wersja opublikowana
w momencie opublikowania
2020-11-28
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